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Introduction to Pectin

Properties

Pectin gelation characteristics can be divided into two main types: High methoxy gelation and low methoxy gelation.

Gelation of high methoxy pectin usually takes plave at a pH of below 3.5 and a total solids content of above 55%. This is the typical gel formed during jam making. high methoxy pectins are characterised by their setting time and the gel strength. Setting time is usually categorised as rapid set, medium set and slow set. High methoxy pectins gel slower as more of the methoxy groups are removed during processing. The gel strength is measured SAG units and the pectin garde is often expressed as the number of units of sugar that a unit of pectin can gel.

Low methoxy pectin is gelled with calcium ions and hence is not dependant on the rpesence of acid or a high solids content. The less ester groups present the more sensitive the pectin becomes to pectin and hence a rapid set, low methoxy pectin as the lowest level of esterification. Amidation can interfere with the gelation causing the gelation to be delayed. Another useful property of amidated pectins is the ability of the gel to reheal after shearing.

Type Methylation level Amidation level Common Description
High Methoxy 74-77 0 Ultra Rapid set
High Methoxy 71-74 0 Rapid set
High Methoxy 66-69 0 Medium Rapid set
High Methoxy 58-65 0 Slow set
Low Methoxy 40 0 Slow set
Low Methoxy 30 0 Rapid set
Amidated 35 15 Slow set
Amidated 30 20 Rapid set


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